The campaign and pre-made character sheets in this are fantastic for a first time DM (like I was!) and first time players! We're still playing the Lost Mine of Phandelver and everyone is loving it. It is a really balanced and well-structured campaign that builds both your player's confidence and your confidence as a DM! Couldn't recommend more :-)
Great way to learn DND. Personally we found you need the player handbook as well.
Also I would get The Explorers Guide To Wildmount for your DM as a next step as they can use the Heroic Chronicle to help you build your character.
It's very nice,quality materials and the designs are attractive